SHELL OIL COMPANY -- 02100, RU 2000 REGULAR UNLEADED GASOLINE  -- 9130-01-089-6745
<pre>=====================  Product Identification  =====================

Product ID:02100, RU 2000 REGULAR UNLEADED GASOLINE
MSDS Date:09/18/1986
FSC:9130
NIIN:01-089-6745
=== Responsible Party ===
Company Name:SHELL OIL COMPANY
Box:4320
City:HOUSTON
State:TX
ZIP:77210
Country:US
Info Phone Num:713-241-4819
Emergency Phone Num:713-473-9461;800-424-9300(CHEMTREC)
Preparer's Name:JOHN P. SEPESI
CAGE:54527
=== Contractor Identification ===
Company Name:SHELL OIL COMPANY
Box:2463
City:HOUSTON
State:TX
ZIP:77210
Country:US
Phone:800-231-6950
CAGE:54527

=============  Composition/Information on Ingredients  =============

Ingred Name:GASOLINE, UNLEADED (ING 2-5 ARE CONSTITUENTS OF INGRED 01)
RTECS #:LY3373000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED

Ingred Name:ALKANES, CYCLOALKANES, ALKENES & AROMATIC HYDROCARBONS
Fraction by Wt: BALANCE

Ingred Name:TOLUENE  (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 0-25%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:XYLENE (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 0-25%
OSHA PEL:100 PPM;150 STEL
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:BENZENE  (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: <5.0%
OSHA PEL:1 PPM;5 STEL
ACGIH TLV:10 PPM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:SUPP DATA:LOSS OF APPETITE, JAUNDICE & SOMETIMES PAIN IN
    UPPER ABDOMEN ON RIGHT SIDE. CHRONIC INHAL EXPOS TO AN (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:UNLEADED MOTOR GAS, WHICH WAS FULLY VAPORIZED, HAS
    PRODUCED KIDNEY & LIVER CANCERS IN SOME MALE RATS. (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: GASOLINE EXPOS ALSO PRODUCED AN INCR OF LIVER CANCER
    @ HIGH DOSES IN FEMALE MICE. EXPOS WERE 6 HRS/DAY, (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: 5 DAYS/WK FOR A TOTAL OF 27 MONTHS. RPTD HIGH LEVEL
    BENZENE EXPOS MAY PRODUCE INJURY OF BLOOD-FORMING (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: TISSUES CAUSING BLOOD ABNORMALITIES & POSSIBLY
    LEUKEMIA; EXPOS TO SUCH HIGH LEVELS ARE NOT ENCOUNTERED (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: IN GASOLINE VAP DUE TO LOW BENZENE CONTENT. INHAL
    STUDIES ON GASOLINE VAPS HAVE CAUSED CNS EFTS IN DOGS (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:@ 10,000 PPM. TOLUENE (108-88-3) APPEARS ON THE NAVY
    LISTING OF OCCUP REPRODUCTIVE HAZ. SEEK CONSULTATION(ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ
    LIST INFORMATION & SAFE HNDLG & EXPOS RECOMMENDATIONS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: OCCURS SPONTANEOUSLY KEEP HEAD BELOW HIPS
    TO PVNT ASPIR OF LIQUID INTO LUNGS. GET MED ATTN. (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:NOTE TO MD: IF >2.0 ML/KG INGESTED & VOMIT HAS NOT
    OCCURRED, EMESIS SHOULD BE INDUCED W/MED SUPERVISION. (ING 16
RTECS #:9999999ZZ

Ingred Name:ING 15:KEEP VICTIM'S HEAD BELOW HIPS TO PVNT ASPIR. IF SYMP
    SUCH AS LOSS OF GAG REFLEX, CONVUL/UNCON OCCUR (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: BEFORE EMESIS, GASTRIC LAVAGE USING A CUFFED
    ENDOTRACHEAL TUBE SHOULD BE CONSIDERED.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC:DIKE & CNTN. H*2O FOG MAY BE USEFUL IN
    SUPPRESSING VAP CLOUD; CNTN RUN-OFF. REMOVE W/VACUUM TRUCKS (ING
    19)
RTECS #:9999999ZZ

Ingred Name:ING 18: OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE
    W/AN ABSORB SUCH AS CLAY, SAND/OTHER SUITABLE MATL; (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:PLACE IN NON-LEAKING CNTNRS FOR PROPER DISP.FLUSH
    AREA W/H*2O TO REMOVE TRACE RESIDUE; DISP OF FLUSH SOLN(ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: AS ABOVE. SML SPILL: TAKE UP W/AN ABSORB & PLACE IN
    NON-LEAKING CNTNRS; SEAL TIGHTLY FOR PROPER DISPOSAL.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL,RAT) > 5 G/KG
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:YES
Health Hazards Acute and Chronic:EYE:MOD IRRIT. SKIN:PRLNGD & RPTD LIQ
    CNTCT CAN CAUSE DEFATTING & DRYING RESULTING IN IRRIT & DERMATITIS.
    INHAL:IRRIT TO NOSE, THROAT & RESP TRACT & ADDNLY, MAY PRODUCE
    LIVER & KIDNEY DMG. INGEST: HAR MFUL/FATAL. MAY RESULT IN VOMIT;
    ASPIR (BRTHG) OF VOMITUS INTO LUNGS MAY RSLT IN ASPIR PNEUMONITIS.
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: KNOWN CARCINOGEN (NTP), GROUP 1
    (IARC), OSHA-REGULATED, GASOLINE, UNLEADED GROUP 2B (IARC)
Effects of Overexposure:HLTH HAZ:EARLY TO MODERATE CNS DEPRESS MAY BE
    EVIDENCED BY GIDDINESS, HDCH, DIZZ, & NAUS; IN EXTREME CASES, UNCON
    & DEATH MAY OCCUR. ASPIR PNEUMONITIS MAY BE EVIDENCED BY COUGHING,
    LABORED BRTHG & CYA NOSIS; IN SEV CASES DEATH MAY OCCUR. KIDNEY DMG
    MAY BE EVIDENCED BY CHANGES IN URINE OUTPUT, URINE APPEARANCE(SUPP
    DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN, & RESP
    DISORDERS MAY BE AGGRAVATED BY EXPOS TO THIS PROD. IMPAIRED LIVER &
    KIDNEY FUNCTION FROM PRE-EXISTING DISORDERS MAY BE AGGRAVATED BY
    EXPOS TO THIS PRODUCT.

=======================  First Aid Measures  =======================

First Aid:EYE: FLUSH W/H*2O FOR @ LST 15 MIN WHILE HOLDING EYELIDS
    OPEN. GET MED ATTN. SKIN: FLUSH W/H*2O WHILE REMOVING CONTAM
    CLTHG/SHOES. FOLLOW BY WASHING W/SOAP & H*2O. DO NOT REUSE
    CLTHG/SHOES UNTIL CLEAN ED. IF IRRIT PERSISTS, GET MED ATTN. INHAL:
    REMOVE VICTIM TO FRESH AIR & PROVIDE O*2 IF BRTHG IS DFCLT. GIVE
    ARTF RESP IF NOT BRTHG. GET MED ATTN. INGEST: DO NOT INDUCE
    VOMITING. IF VOMIT (ING 14)

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3%
Upper Limits:7.6%
Extinguishing Media:H*2O FOG, FOAM, DRY CHEM/CO*2. DO NOT USE A DIRECT
    STREAM OF H*2O. PROD WILL FLOAT & CAN BE REIGNIT ON SURF OF H*2O.
Fire Fighting Procedures:DANGER. EXTREMELY FLAMM. CLEAR FIRE AREA OF
    UNPROT PERSONNEL & ISOLATE. DO NOT ENTER CONFINED FIRE SPACE
    WITHOUT NIOSH/MSHA APPRVD SCBA & FULL PROT (SUPP DATA)
Unusual Fire/Explosion Hazard:VAP ARE HVR/AIR ACCUMLATING IN LOW AREAS
    TRAVELING ALONG THE GROUND AWAY FROM THE HNDLG SITE. DO NOT WELD,
    HEAT/DRILL ON/NEAR CNTNR. IF EMERGENCY (SUPP DATA)

==================  Accidental Release Measures  ==================

Spill Release Procedures:DANGER. EXTREMELY FLAMM. ELIM ALL IGNIT
    SOURCES. GROUND HNDLG EQUIP TO PVNT SPARKING. LRG SPILLS:ISOLATE
    HAZ AREA & DENY ENTRY TO UNNEC PERSONNEL. WEAR APPROP NIOSH/MSHA
    APPRVD RESP & PROT CLTHG. SHUT  OFF SOURCE OF LEAK ONLY IF SAFE TO
    DO SO.(ING 18)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DANGER. EXTREMNELY FLAMMABLE. AVOID
    HEAT/SPARKS/OPEN FLAMES, INCLUDING PILOT LIGHTS, & STRONG OXIDIZING
    AGENTS. USE EXPLO-PROOF VENT TO PVNT ACCUM.
Other Precautions:ALL HNDLG EQUIP MUST BE GROUNDED TO PVNT SPARKING.
    HARMFUL/FATAL IF SWALLOWED. DO NOT SIPHON GASOLINE BY MOUTH. FOR
    USE AS A MOTOR FUEL ONLY. DO NOT USE AS A CLEANING SOLV/FOR OTHER
    NON-MOTOR FUEL USE S.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:UNDER CNDTNS OF POTENTIAL HIGH EXPOS, USE
    NIOSH/MSHA APPRVD RESP. PER 29 CFR 1910.134 USE EITHER NIOSH/MSHA
    APPRVD ATMOSPHERE-SUPPLYING RESP/AIR-PURIFYING RESP FOR ORGANIC
    VAPS. FOR SERVICE STATION PE RSONNEL PROT, SEE SPEC FOR HNDLG &
    USE.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
    VAPOR CONCENTRATIONS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH W/SOAP & H*2O BEFORE EATING, DRINKING,
    SMOKING/USING TOILET FACILITIES. LAUNDER CONTAM CLTHG BEFORE REUSE.
Supplemental Safety and Health
SPEC GRAV:0.72-0.76 (H*2O=1).FIRE FIGHT PROC: EQUIP.COOL FIRE EXPOS
    CNTNRS W/H*2O.EXPLO HAZ:SITUATIONS REQUIRE DRILLING, ONLY TRAINED
    EMERGENCY PERSONNEL SHOULD DRILL.WASTE DISP METH:RECYCLING R
    ECOMMENDED.DISP OF I/A/W FED, STATE, LOC REGS. EFTS OF OVEREXP:OR
    EDEMA. LIVER DMG MAY BE EVIDENCED BY (ING 6)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:100F,38C
Vapor Pres:7-14.5 PSI
Vapor Density:3.5
Spec Gravity:SUPP DATA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE COLOR, CLEAR AND BRIGHT LIQUID. HYDROCARBON
    ODOR.
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES. PREVENT
    VAPOR ACCUMULATION.
Hazardous Decomposition Products:CO AND OTHER UNIDENTIFIED ORGANIC
    COMPOUNDS CAN BE FORMED UPON COMBUSTION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:MATL IS PROD & NOT WASTE. IF DISCARDED/INTENDED
    TO BE DISCARDED AS IS, IT IS LIQ IGNIT HAZ WASTE DEFINED IN RCRA
    (40 CFR 261.21). EPA HAZ WASTE NO IS D001. FREE LIQ IGNIT WASTES
    BANNED FROM DISP BY LA NDFILLING BULK/IN CNTNRS. RECOVER OR (SUPP
    DATA)

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